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How To Calculate Atomic Mass Using Isotopes

Atomic Mass Formula:

\[ \text{Atomic mass} = \sum (\text{isotope mass} \times \text{fractional abundance}) \]

1. What is Atomic Mass?

Atomic mass is the weighted average mass of all naturally occurring isotopes of an element, taking into account their relative abundances. It's expressed in atomic mass units (amu) and appears on the periodic table for each element.

2. How to Calculate Atomic Mass from Isotopes

The formula for calculating atomic mass from isotopes is:

\[ \text{Atomic mass} = \sum (\text{isotope mass} \times \text{fractional abundance}) \]

Where:

  • Isotope mass — Mass of each isotope in atomic mass units (amu)
  • Fractional abundance — Relative abundance of each isotope (between 0 and 1)
  • The sum is taken over all naturally occurring isotopes

3. Understanding Isotopes and Abundance

Isotopes are atoms of the same element with different numbers of neutrons, resulting in different masses. Natural abundance refers to the percentage of each isotope found in nature.

Example: Chlorine has two major isotopes - Cl-35 (75.77% abundance) and Cl-37 (24.23% abundance). Its atomic mass is calculated as (35 × 0.7577) + (37 × 0.2423) = 35.45 amu.

4. Using the Calculator

Instructions:

  1. Enter the mass of each isotope in atomic mass units (amu)
  2. Enter the fractional abundance (between 0 and 1) for each isotope
  3. Add or remove isotope fields as needed
  4. Click "Calculate" to get the weighted average atomic mass

5. Frequently Asked Questions (FAQ)

Q1: Why is atomic mass not a whole number?
A: Atomic mass is a weighted average of all naturally occurring isotopes, which rarely results in a whole number.

Q2: What's the difference between mass number and atomic mass?
A: Mass number is the sum of protons and neutrons in a specific isotope (always a whole number), while atomic mass is the weighted average of all isotopes.

Q3: How do I convert percentage abundance to fractional abundance?
A: Divide the percentage by 100. For example, 75.77% becomes 0.7577.

Q4: Why do we use weighted average instead of simple average?
A: Weighted average accounts for the different natural abundances of isotopes, giving a more accurate representation of the element's mass as it occurs in nature.

Q5: Can I use this for radioactive isotopes?
A: This calculator is designed for stable, naturally occurring isotopes. For radioactive isotopes, their typically negligible natural abundance means they contribute little to atomic mass calculations.

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